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Variable morphologies of self-assembled metal-complexed lauroyl-glycylglycine in the presence of montmorillonite-silica nanowires

D. VARASTEANU1, M. C. COROBEA1,* , M. GHIUREA1, S. POP1, I. CHICAN1, D. FLOREA1, A. PISCUREANU1, I. CALINESCU2

Affiliation

  1. National Research & Development Institute for Chemistry and Petrochemistry ICECHIM-Bucharest, Splaiul Independentei 202, 060021, Romania
  2. University Politehnica from Bucharest, Faculty of Applied Chemistry and Materials Sciences, 1-7 Gheorghe Polizu, Bucharest, 011061, Romania

Abstract

Synthesis of cobalt (II) and Ni (II) complexes of lauroyl-glycylglycine in the presence of montmorillonite-silica nanowires was followed in terms of variable morphologies induced by self-assembling phenomena. The interactions between different metal complexes and the montmorillonite-silica nanowires segments were observed by FTIR, TGA, DSC and SEM results. These interactions induced variable morphologies (sheet-like, ribbon-like, tube-like and fiber-like). Variable morphologies, physical and chemical nature and the thermal stability recommend this new class of hybrids in catalysis applications..

Keywords

Self-assembling, Metal complex, Silica nanowires.

Citation

D. VARASTEANU, M. C. COROBEA, M. GHIUREA, S. POP, I. CHICAN, D. FLOREA, A. PISCUREANU, I. CALINESCU, Variable morphologies of self-assembled metal-complexed lauroyl-glycylglycine in the presence of montmorillonite-silica nanowires, Optoelectronics and Advanced Materials - Rapid Communications, 7, 11-12, November-December 2013, pp.991-996 (2013).

Submitted at: Sept. 2, 2013

Accepted at: Nov. 7, 2013