Abstract
Samarium doped Polyvinyl Alcohol (PVA) films were prepared and the optical properties of the films were investigated. By
applying Judd-Ofelt theory the Ω parameters were obtained from the absorption spectrum. Various radiative parameters like
transition probability for each level (AJ), total transition probability (AT), branching ratio (βR), radiative lifetime (τR) and
absorption cross section (σA) were calculated. The theoretically obtained branching ratio and integrated absorption cross
section are found to be greater for the transition 4G7/2->6H11/2. The emission spectra obtained at 595nm supports the
theoretical results with high-stimulated emission cross-section (σE) and high optical gain.
Keywords
Rare earth, Samarium, Polyvinyl alcohol, Judd-Ofelt Parameters.
Citation
A. K. ADIYODI, P. V. JYOTHY, T. F. TONEY, GIJO JOSE, N. V. UNNIKRISHNAN, Spectroscopic characterization of Sm3+ ions in PVA film, Optoelectronics and Advanced Materials - Rapid Communications, 1, 6, June 2007, pp.281-286 (2007).
Submitted at: March 19, 2007
Accepted at: April 25, 2007