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Ship-in-bottle porphyrin – zeolite nanomaterials

V. FARAON1,2,* , R. M. ION1,2

Affiliation

  1. Valahia University, Unirii Blvd. 18-20, 130024, Targoviste, Romania
  2. ICECHIM, 202 Splaiul Independentei, 060021, Bucharest, Romania

Abstract

In this paper, some metallo-porphyrins, like Co(II)-5,10,15,20-tetra-p-phenyl-porphyrin (CoTPP) and Co(II)- tetramethylphenylporphyrin (CoTMPP), were synthesized and encapsulated in different zeolites (X-71, MCM-41 etc.). In the encapsulated form, they exhibit photocatalytic properties and can also be used in the photodynamic therapy of cancer. The synthesized compounds were analyzed by means of some analytical methods, the most important being UV – spectroscopy and X-ray diffraction. Some preliminary photodynamic experiments of these new systems have been achieved (viability and proliferation) on cellular line (EL-4 and K562), by using He-Ne laser.

Keywords

Metallo-porphyrins, Zeolite, Encapsulation.

Citation

V. FARAON, R. M. ION, Ship-in-bottle porphyrin – zeolite nanomaterials, Optoelectronics and Advanced Materials - Rapid Communications, 4, 8, August 2010, pp.1135-1140 (2010).

Submitted at: July 30, 2010

Accepted at: Aug. 12, 2010