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Preparation and anti-corrosive performance of polypyrrole composites redoped with zinc phosphate

XUE SHOUQING1,* , LIU QINGHUA1

Affiliation

  1. Institute of Fine Chemicals, Heze University, Heze 274015, Shandong, China Department of Chemistry and Chemical Engineering, Heze University, Heze 274015, Shandong, China

Abstract

As polypyrrole (Ppy) has unique doping and dedoping characteristics, the new nano-materials redoped and doped Ppy composites with special anti-corrosive functional groups were successfully prepared by direct oxidation in the stainless steel(SS) surface respectively. The microcomic structure, morphology and anti-corrosive performance of the redoped Ppy were characterized by Cyclic voltammetry(CV), scanning electron microscopy(SEM), Polarization curves(PC) and electrochemical impedance spectroscopy (EIS), and compared with a doped and undoped Ppy, and their anti-corrosion mechanism were investigated theoretically. The results show that, the stainless steel surface covered with redoped and doped Ppy composites had good anti-corrosive performance, the redoped Ppy composites had the best. The corrosion potential of the redoped Ppy composite was increased by about 0.989V and the corrosion current is reduced by about 2 orders of magnitude to pure Ppy. The dense membrane structure of the redoped Ppy significantly increased, membrane defects significantly reduced, the best corrosion resistance, so it has a better anti-corrosion behavior..

Keywords

Redoped, Zinc phosphate, anti-corrosive performance, Ppy.

Citation

XUE SHOUQING, LIU QINGHUA, Preparation and anti-corrosive performance of polypyrrole composites redoped with zinc phosphate, Optoelectronics and Advanced Materials - Rapid Communications, 9, 11-12, November-December 2015, pp.1483-1486 (2015).

Submitted at: Sept. 3, 2015

Accepted at: Oct. 28, 2015