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Potential red-emission phosphor (Ca, Sr)(Mo, W)O4:Eu3+, Y3+ and charge compensation impact on its luminescent property

FABIN CAO1,* , LUHONG WEI1, LIAOSHA LI1, XINGRONG WU1

Affiliation

  1. Anhui Provincial Key Laboratory of Metallurgical Engineering &Resources Recycling (Anhui University of Technology), Maanshan, Anhui, 243002, PR China

Abstract

Eu3+-Y3+ co-doped (Sr0.88-x-1.5yCaxEuyY0.08)(Mo0.2 W0.8)O4(x=0.20, 0.30, 0.40, 0.50, 0.60, 0.70. y=0.02, 0.04, 0.06, 0.08, 0.10, 0.12, 0.16, 0.20) were prepared by sol-gel method, and their crystal structures and luminescent properties were investigated. Through XRD, photoluminescence spectra analyses and powder size measurements, changing Ca2+ concentration, Eu3+ concentration and charge compensators components were performed for optimization its emission property. It was found that, with 2 mol% 0.6Li2CO3-0.4K2CO3 charge compensation, (Sr0.26Ca0.5Eu0.08Y0.08)(Mo0.2 W0.8)O4 possesses better emission property than the commercial phosphor Y2O2S:Eu3+..

Keywords

Charge compensators, Optical properties, Sol-gel method.

Citation

FABIN CAO, LUHONG WEI, LIAOSHA LI, XINGRONG WU, Potential red-emission phosphor (Ca, Sr)(Mo, W)O4:Eu3+, Y3+ and charge compensation impact on its luminescent property, Optoelectronics and Advanced Materials - Rapid Communications, 8, 11-12, November-December 2014, pp.1135-1140 (2014).

Submitted at: March 23, 2014

Accepted at: Nov. 13, 2014