Abstract
Zinc oxide Mn doped nanobelts have been synthesized by chemical precipitation technique using zinc acetate and
manganese acetate as a starting material. Electron microscopy observations indicate that the length of nanobelts are
ranging from 100μm to 200μm. X-Ray diffraction pattern confirms the wurtzite structure. Nitrogen laser having high peak
power (1MW), pulsed (5-7ns) and (λ =337.1nm) has been used for the time resolved luminescence studies and
spectroflourometer for steady state photoluminescence measurements. From the decay curves of time resolved laser
induced photoluminescence various important optical parameters such as excited state life time, trap depth value, decay
constant and integrated cross section and dipole moment have been calculated and reported in this paper. Einstein’s
spontaneous and stimulated coefficient values obtained from decay curves indicate the probability of transitions from
various traps. Selective excitation of the levels can make ZnO a best suited laser medium. Various parameters have been
calculated from recorded luminescence decay curves. Crystallographic and morphological characteristics have been
studied using X-Ray diffraction (XRD) and electron microscopy (SEM and TEM).
Keywords
Nanobelts, Photoluminescence, Laser, Time resolved.
Citation
D. KUMAR, S. KUMAR, A. GUPTA, H. S. BHATTI, Photoluminescence decay kinetics of ZnO:Mn nanobelts, Optoelectronics and Advanced Materials - Rapid Communications, 2, 9, September 2008, pp.543-548 (2008).
Submitted at: July 17, 2008
Accepted at: Aug. 28, 2008