"

Cookies ussage consent

Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our site without changing the browser settings you grant us permission to store that information on your device.

Novel Carbon paste selective material for potassium detection

C. VARODI1,2,* , N. TOSA1

Affiliation

  1. National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath Str., RO-400293 Cluj-Napoca, Romania
  2. “Babeş-Bolyai”University, Physical Chemistry Department, 11 Arany Janos Str., RO-400028 Cluj-Napoca, Romania

Abstract

Potassium ion plays a crucial role for the organisms life. Its detection is performed usually by potassium selective electrodes (PSE) having membranes made of a polymer matrix (such as PVC) incorporating macrocyclic compounds as ionophore. We propose a novel potassium selective material (PSM) based on a new synthesized crown-ether ionophore incorporated in carbon paste conductive matrix (PSM-CP). Electrochemical measurements proved the affinity of PSM-CP for the potassium cation, which is selectively bound by entrapping in the crown-ether cavity. The results are comparable with those obtained by using a PSE based on PVC-ionophore membrane.

Keywords

Crown-ether, Ionophore, Optical spectroscopic methods, Potassium cation detection, Electrochemistry.

Citation

C. VARODI, N. TOSA, Novel Carbon paste selective material for potassium detection, Optoelectronics and Advanced Materials - Rapid Communications, 4, 11, November 2010, pp.1724-1727 (2010).

Submitted at: Nov. 3, 2010

Accepted at: Nov. 10, 2010