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New considerations on mechanisms involved in M-effect in electropositive-electronegative gas mixtures

G. MUSA1, L. C. CIOBOTARU1,*

Affiliation

  1. National Institute R&D for Laser, Plasma and Radiation Physics, PO Box MG 36, 077125, Bucharest, Romania

Abstract

In some previously published papers we reported the possibility of obtaining nearly monochrome radiation spectra using A.C. /D.C. discharges in electronegative-electropositive gas mixtures at pressures bigger than 20 Torr. We called this effect the M-effect. In order to characterize the effect we introduced the M parameter defined as the ratio of the relative intensities of the radiation of two wavelengths of recorded spectra. One spectral line is called dominant line, having a spectacular growing at the addition of the electronegative gas and the other one is a common spectral line arbitrary chosen from the spectrum, which is considered the reference line. Using this parameter, various recorded spectra can be compared and thus, the M value can be considered a qualitative measure of the M-effect “intensity”. The main mechanism proposed by us which determines the appearance of M-effect is a resonant three-body collision reaction. This type of reaction has one of the largest cross-section known, about 10-12 cm2. According to the magnitude order of the defect energy reaction it can explain the appearance of one dominant spectral line, e.g. (Ne+H2) gas mixture, or at least two dominant spectral lines, e.g. (He+O2/Cl2) or (Ar+H2) gas mixtures.

Keywords

M-effect, Three body reaction, Resonant polar recombination, Defect energy reaction.

Citation

G. MUSA, L. C. CIOBOTARU, New considerations on mechanisms involved in M-effect in electropositive-electronegative gas mixtures, Optoelectronics and Advanced Materials - Rapid Communications, 1, 3, March 2007, pp.137-142 (2007).

Submitted at: Jan. 1, 2007

Accepted at: Feb. 14, 2007