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Influence of reactant concentration on nano crystalline PbS thin films prepared by Chemical Spray Pyrolysis

R. THIAGARAJAN1, M. MAHABOOB BEEVI1, M. ANUSUYA2, T. RAMESH1,*

Affiliation

  1. Department of Physics, Urumu Dhanalakshmi College, Kattur, Trichy, Tamilnadu, India
  2. Department of Physics, Trichy Engineering College, Konalai, Trichy, India

Abstract

Nanocrystalline PbS thin films were prepared by simple and cost effective chemical spray pyrolysis (CSP) technique. Lead acetate and Thiourea were used as a source of Pb and S respectively. The structural and optical properties of the PbS films were studied. Structural cubic phases of the PbS thin films were identified by X-ray diffraction with preferential orientation along (200) plane. The average grain size of the film is calculated using Scherer’s relation and it is in the order of nanometers. The optical properties of the films were studied by measuring their optical Absorbance and transmittance as a function of wavelength. UV-VIS spectrum of the film showed that the optical band gap decreases with increase in the molarities of precursor solution. The surface morphological studies of the films were analyzed by scanning electron microscope..

Keywords

PbS thin film, Xrd, Optical, Sem.

Citation

R. THIAGARAJAN, M. MAHABOOB BEEVI, M. ANUSUYA, T. RAMESH, Influence of reactant concentration on nano crystalline PbS thin films prepared by Chemical Spray Pyrolysis, Optoelectronics and Advanced Materials - Rapid Communications, 6, 1-2, January-February 2012, pp.132-135 (2012).

Submitted at: Dec. 26, 2011

Accepted at: Feb. 20, 2012