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Fabrication of perovskite solar cells in ambient air by employing poly (triarylamine) as the hole transport layer

GUILIN LIU1,2,3,* , XI XI1, WEIFU DONG2,3

Affiliation

  1. School of Science, Jiangnan University, WuXi, China, 214122
  2. School of Chemical and Materials Engine ering, Jiangnan University , Wuxi , China, 214122
  3. National International Joint Research Center for Photoresponse Functional Molecular Materials Jiangnan University, Wuxi , China, 2 14122

Abstract

Poly --(triarylamine) ( was employed as the hole transport layer s (HTL s ) to fabricate perovskite solar cells ( in ambient air wherein the temperature and relative humidity were controlled at 30 and 30%, respectively. In comparison to PSC s based on spiro OMeTAD HTL s the statistical power conversion efficiency (PC E) of ambient air fabricated solar cells was close to solar cell s which were fabricated in nitrogen . It indicate d the PTAA layer s w ere less sensitive in air than that of spiro OMeTAD during the fabrication process The PCE was around 12% in average for PS C s with PTAA HTLs. Additionally , i t was found that oxygen aging can further improve the PCE to 1 4 % in However, though the stability of HTLs were improved by employing PTAA, the perovskite crystals limits the long term stability of perovskite solar cells. According to our experiments, after 2 weeks degradation in air, the PCE of all PSCs were dropped due to the decomposition of perovskite crystals. As a result, additional encapsulation treatments are worthy investigated for the long term stability of perovskite solar cells..

Keywords

Solar energy materials H ole transport layer A mbient air.

Citation

GUILIN LIU, XI XI, WEIFU DONG, Fabrication of perovskite solar cells in ambient air by employing poly (triarylamine) as the hole transport layer, Optoelectronics and Advanced Materials - Rapid Communications, 12, 11-12, November-December 2018, pp.687-693 (2018).

Submitted at: Feb. 27, 2018

Accepted at: Nov. 29, 2018