Abstract
Lead potassium dysprosium niobate (PKDN) has been prepared by a standard conventional ceramic route. Material
formation has been confirmed by X-ray diffraction (XRD) studies. The variation of dielectric constant with temperature is
explained considering the space-charge polarization. Complex impedance spectroscopy (CIS) analysis has been carried
out to investigate its electrical properties as a function of frequency and temperature. CIS analysis has indicated the
electrical behavior of the material sample shows negative temperature coefficient of resistance (NTCR) typical to a
semiconductor behavior. Impedance studies indicated the presence of temperature dependant relaxation process in the
material with a spread of relaxation time. Modulus analysis reveals the possibility of hopping mechanism for electrical
processes in the system. The frequency dependant ac conductivity at different temperatures showed the conduction
process is thermally activated process.
Keywords
Ceramics, Solid-state reaction, X-ray diffraction, Ferroelectric, Piezoelectric, Impedance, Electric modulus, Conductivity.
Citation
K. SAMBASIVA RAO, D. MADHAVA PRASAD, P. MURALI KRISHNA, T. SWARNA LATHA, JOON HYUNG LEE, Electrical and electromechanical studies on tungstenbronze electroceramic: lead potassium dysprosium niobate, Optoelectronics and Advanced Materials - Rapid Communications, 1, 10, October 2007, pp.510-519 (2007).
Submitted at: Aug. 16, 2007
Accepted at: Aug. 30, 2007