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Effect on microstructure of TiO 2 rate in Al 2 O 3 TiO 2 composite coating produced using plasma spray method

S. ISLAK1,* , S. BUYTOZ2, E. ERSOZ2, N. ORHAN2, J. STOKES3, M. SALEEM HASHMI3, I. SOMUNKIRAN2, N. TOSUN2

Affiliation

  1. Cide Rifat Ilgaz Vocational High School, Kastamonu University, 37600 Kastamonu, Turkey
  2. Metallurgy and Materials Engineering, Technology Faculty, Firat University, 23119 Elazig, Turkey
  3. School of Mechanical and Manufacturing Engineering, DCU, Dublin, Ireland

Abstract

In this study, Al2O3-TiO2 composite coatings were thermally sprayed on the SAE 1040 steel using atmospheric plasma spray (APS) process of mixed different rates micron–sized TiO2 and micron-sized Al2O3 powders. The effects of TiO2 addition on the microstructure, phase compositions and microhardness of the coatings were investigated by using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray diffractometry (XRD) and microhardness tester. The results show that the Al2O3-TiO2 composite coatings consists of both fully melted regions and partially melted regions, and the fully melted region has a lamellar-like structure. Phase transformations from mainly stable α-Al2O3 and anatase-TiO2 in the powders to predominant metastable γ-Al2O3, rutile-TiO2 and Al2TiO5 phase in the Al2O3-TiO2 composite coatings were observed. It was determined that the pore content decreased with the increased in the TiO2 powder rate. The microhardness of the coating layers was 3-4.5 times higher than substrate material. The average microhardness values of the coatings were found to reach 650-860 HV..

Keywords

Plasma spray, Ceramic coating, γ-Al2O3, Rutile-TiO2.

Citation

S. ISLAK, S. BUYTOZ, E. ERSOZ, N. ORHAN, J. STOKES, M. SALEEM HASHMI, I. SOMUNKIRAN, N. TOSUN, Effect on microstructure of TiO 2 rate in Al 2 O 3 TiO 2 composite coating produced using plasma spray method, Optoelectronics and Advanced Materials - Rapid Communications, 6, 9-10, September-October 2012, pp.844-849 (2012).

Submitted at: May 15, 2012

Accepted at: Sept. 20, 2012