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Antiferromagnetic exchange interactions in asymmetrically bridged dinuclear Fe(III) complexes by phenoxo and metoxo groups: magnetic field dependence of magnetisation

A. BAYRI1,* , S. EKMEKCI2

Affiliation

  1. Adiyaman University, Arts and Science Faculty, Department of Physics, Tr-02040 Adiyaman, Turkey
  2. Adiyaman University, Faculty of Education, Department of Science Education, Tr-02040 Adiyaman, Turkey

Abstract

In this study the antiferromagnetic interactions in recently synthesized dinuclear Fe(III) complex has been investigated in a magnetic field. For this purpose the magnetic moment of Fe(III) ions has been calculated in the vicinity of the magnetic field. Using the reported coupling constant, it was shown that the magnetic moment takes a ladder like behavior below a certain temperature. It was also shown that the saturation magnetization can be more easily obtained for small coupling constant.

Keywords

Magnetization, Magnetic susceptibility, Antiferromagnetic coupling, Fe(III) dimmer.

Citation

A. BAYRI, S. EKMEKCI, Antiferromagnetic exchange interactions in asymmetrically bridged dinuclear Fe(III) complexes by phenoxo and metoxo groups: magnetic field dependence of magnetisation, Optoelectronics and Advanced Materials - Rapid Communications, 4, 5, May 2010, pp.740-743 (2010).

Submitted at: April 2, 2010

Accepted at: May 20, 2010