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S. VIJAYALAKSHMI1, S. KALYANARAMAN1,*
The new organic NLO material of hexamine: m – cresol material (1:2) has been synthesized by slow – evaporation technique. The good crystalline nature of the material is identified through Powder XRD analysis. FT – IR tool is used to confirm the formation of O – H --- N hydrogen bonding and non proton transfer of the material. The charge transfer (CT) through hydrogen bonding is also established. The possible vibration modes are predicted through factor group analysis theoretically. The charge transfer interaction is confirmed by UV -Vis analysis in addition to the bathochromic shift behavior. That the candidate has greater second harmonic generation (SHG) efficiency than the KDP is identified through Powder Kurtz – Perry technique..
Organic material, Charge transfer (CT), Second harmonic generation (SHG).
S. VIJAYALAKSHMI, S. KALYANARAMAN, A novel class of new organic NLO hexamine: m – cresol material, Optoelectronics and Advanced Materials - Rapid Communications, 7, 7-8, July-August 2013, pp.545-548 (2013).
Submitted at: Jan. 18, 2013
Accepted at: July 11, 2013
Optoelectronics and Advanced Materials - Rapid Communications
(2022): 0.5 - 2022 Journal Citation Reports (Clarivate Analytics, 2023)
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