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Characterization of CdSe films prepared by chemical bath deposition method

H. METIN1,* , S. ERAT1, M. ARI2, M. BOZOKLU2

Affiliation

  1. University of Mersin, Department of Physics, Mersin, Turkey
  2. University of Erciyes, Department of Physics, Kayseri, Turkey

Abstract

The optical, structural and electrical properties of Cadmium Selenide (CdSe) thin films were deposited by a simple and inexpensive method, chemical bath deposition (CBD), have been investigated. The optical measurements have been obtained by using the UV-Visible spectrophotometer and the optical band gap energy (Eg) was calculated from the absorption spectra as 1.83 eV and 1.76 eV for the chemically deposited CdSe thin films at 60 °C and 70 °C, respectively. The samples were characterized by using the X-ray diffraction method, the scanning electron microscope (SEM) and the energy dispersive X-ray analysis (EDX). The grain size of the films depend on the annealing temparature and is situated in the range 86 - 820 Å from X-ray analysis. The electrical resistivity and conductivity of the CdSe films have been determined by using four-point probe technique in the temperature range between 310–640 K. The electrical resistivities were found in the order of 106 Ω-cm at room temperature and in order of 104 Ω-cm at 640 K. The activation energy was found to be about 0.27 eV - 0.41 eV and the temperature coefficient of electrical resistivity was found to be about -3.04x10-3 K-1 and -3.27x10-3 K-1 for room temperature and 640 K, respectively.

Keywords

Characterization, Thin film, CdSe, Four-point probe method.

Citation

H. METIN, S. ERAT, M. ARI, M. BOZOKLU, Characterization of CdSe films prepared by chemical bath deposition method, Optoelectronics and Advanced Materials - Rapid Communications, 2, 2, February 2008, pp.92-98 (2008).

Submitted at: Jan. 24, 2008

Accepted at: Feb. 11, 2008