Abstract
The optical, structural and electrical properties of Cadmium Selenide (CdSe) thin films were deposited by a simple and
inexpensive method, chemical bath deposition (CBD), have been investigated. The optical measurements have been
obtained by using the UV-Visible spectrophotometer and the optical band gap energy (Eg) was calculated from the
absorption spectra as 1.83 eV and 1.76 eV for the chemically deposited CdSe thin films at 60 °C and 70 °C, respectively.
The samples were characterized by using the X-ray diffraction method, the scanning electron microscope (SEM) and the
energy dispersive X-ray analysis (EDX). The grain size of the films depend on the annealing temparature and is situated in
the range 86 - 820 Å from X-ray analysis. The electrical resistivity and conductivity of the CdSe films have been determined
by using four-point probe technique in the temperature range between 310–640 K. The electrical resistivities were found in
the order of 106 Ω-cm at room temperature and in order of 104 Ω-cm at 640 K. The activation energy was found to be about
0.27 eV - 0.41 eV and the temperature coefficient of electrical resistivity was found to be about -3.04x10-3 K-1 and
-3.27x10-3 K-1 for room temperature and 640 K, respectively.
Keywords
Characterization, Thin film, CdSe, Four-point probe method.
Citation
H. METIN, S. ERAT, M. ARI, M. BOZOKLU, Characterization of CdSe films prepared by chemical bath deposition method, Optoelectronics and Advanced Materials - Rapid Communications, 2, 2, February 2008, pp.92-98 (2008).
Submitted at: Jan. 24, 2008
Accepted at: Feb. 11, 2008